和/跟 + Person + 说话
The verb 说话 (shuōhuà) means "to speak" or "to talk." It is a separable verb, meaning other elements can be inserted between 说 and 话. The pattern 和她说话 means "to talk to/with her."
上课的时候不要说话。
Shàngkè de shíhou bú yào shuōhuà.
Don't talk during class.
她喜欢和朋友说话聊天。
Tā xǐhuan hé péngyou shuōhuà liáotiān.
She likes talking and chatting with friends.
他说话的声音很好听。
Tā shuōhuà de shēngyīn hěn hǎotīng.
He has a very pleasant speaking voice.